They unlock in the Zoologist's wares after a certain amount of Bestiary progress has been obtained. I think it is around 30%. Is your Bestiary progress around that amount or higher?
If she isn't selling anything, would you be able to upload your World file here?
In your Bestiary, there is a progress bar showing the percentage of all enemies & NPCs you've discovered in the game. If you mouse over this bar indicated in the screenshot, it will show you your Bestiary % completion:
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