Charmander27
Queen Bee
Those balls existed in X/Y/ΩR/αS, you can transfer Pokémon up from HG/SS and breed to have those balls.
Though, it has been highly speculated that there will be a mechanic to change the ball your Pokémon resides in with this generation, so I wouldn't count it out that you can use them. Fast Balls, Luxury Balls, and Love Balls are my favorite types, so it would be nice to have better access to the other two.
[/SPOILER
Though, it has been highly speculated that there will be a mechanic to change the ball your Pokémon resides in with this generation, so I wouldn't count it out that you can use them. Fast Balls, Luxury Balls, and Love Balls are my favorite types, so it would be nice to have better access to the other two.
[/SPOILER