Get a coil of super thin string, make sure it's clean, cut it into uneven strands and sparsely decorate food with it.
"Edible" gold leaves just like what they use for fine dining, but plot twist! They're not actually edible!
I would suggest a laxative to annoy, and refuse to list a poison that would satisfy the second question.
Antidiarrheals to annoy. Having to sit on the toilet for forever is annoying. As for poisons, I know too many to list and they all have varying affects.